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Nonfiction: [[Marc Julia (nonfiction)|Marc Julia]]. | Nonfiction: [[Marc Julia (nonfiction)|Marc Julia]]. | ||
== In the News == | |||
<gallery> | |||
</gallery> | |||
== Fiction cross-reference == | |||
* [[Crimes against chemical constants]] | |||
* [[Gnomon algorithm]] | |||
* [[Gnomon Chronicles]] | |||
* [[The Julia Olefination]] - 1973 thriller film starring chemists [[Marc Julia (nonfiction)|Marc Julia]] and [[Jean-Marc Paris (nonfiction)|Jean-Marc Paris]], who report a novel olefin synthesis in which β-acyloxysulfones are reductively eliminated to the corresponding di-, tri-, or tetrasubstitued alkenes. [[Basil Lythgoe (nonfiction)|Basil Lythgoe]] and [[Philip J. Kocienski (nonfiction)|Philip J. Kocienski]] explore the scope and limitation of the reaction, today formally known as the Julia-Lythgoe olefination. The reaction involves the addition of a sulfonyl-stabilized carbanion to a carbonyl compound, followed by elimination to form an alkene. In the initial versions of the reactions, the elimination is done under reductive conditions. Later in the film, a modified version that avoids this step is developed. The former version is sometimes referred to as the Julia-Lythgoe olefination, whereas the latter is called the Julia-Kocienski olefination. In the reductive variant, the adduct is usually acylated and then treated with a reducing agent, such as sodium amalgam or SmI2. | |||
== Nonfiction cross-reference == | |||
* [[Georges Dupont (nonfiction)]] | |||
* [[Gaston Julia (nonfiction)]] - brother | |||
* [[Ian Heilbron (nonfiction)]] | |||
== External links == | |||
* [https://en.wikipedia.org/wiki/Marc_Julia Marc Julia] @ Wikipedia | |||
== Attribution == | |||
* https://www.chimie.ens.fr/historique/ | |||
[[Category:Nonfiction (nonfiction)]] | |||
[[Category:Chemists (nonfiction)]] | |||
[[Category:People (nonfiction)]] | |||
[[Category:Photographs (nonfiction)]] | |||
[[Category:Portraits (nonfiction)]] | |||
[[Category:Scientists (nonfiction)]] |
Latest revision as of 04:22, 19 March 2020
Nonfiction: Marc Julia.
In the News
Fiction cross-reference
- Crimes against chemical constants
- Gnomon algorithm
- Gnomon Chronicles
- The Julia Olefination - 1973 thriller film starring chemists Marc Julia and Jean-Marc Paris, who report a novel olefin synthesis in which β-acyloxysulfones are reductively eliminated to the corresponding di-, tri-, or tetrasubstitued alkenes. Basil Lythgoe and Philip J. Kocienski explore the scope and limitation of the reaction, today formally known as the Julia-Lythgoe olefination. The reaction involves the addition of a sulfonyl-stabilized carbanion to a carbonyl compound, followed by elimination to form an alkene. In the initial versions of the reactions, the elimination is done under reductive conditions. Later in the film, a modified version that avoids this step is developed. The former version is sometimes referred to as the Julia-Lythgoe olefination, whereas the latter is called the Julia-Kocienski olefination. In the reductive variant, the adduct is usually acylated and then treated with a reducing agent, such as sodium amalgam or SmI2.
Nonfiction cross-reference
External links
- Marc Julia @ Wikipedia
Attribution
File history
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